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dc.contributor.authorPellicer Balsalobre, José Antonio
dc.contributor.authorRodríguez López, María Isabel
dc.contributor.authorFortea, María Isabel
dc.contributor.authorLucas Abellán, Carmen
dc.contributor.authorMercader Ros, María Teresa
dc.contributor.authorLópez Miranda, Santiago
dc.contributor.authorGómez López, Vicente Manuel
dc.contributor.authorSemeraro, Paola
dc.contributor.authorCosma, Pinalysa
dc.contributor.authorFini, Paola
dc.contributor.authorFranco, Esther
dc.contributor.authorFerrándiz, Marcela
dc.contributor.authorPérez, Enrique
dc.contributor.authorFerrándiz, Miguel
dc.contributor.authorNúñez Delicado, Estrella
dc.contributor.authorGabaldón, José Antonio
dc.date.accessioned2019-03-25T09:59:35Z
dc.date.available2019-03-25T09:59:35Z
dc.date.issued2019
dc.identifier.isbn2073-4360
dc.identifier.urihttp://hdl.handle.net/10952/3838
dc.description.abstractβ-cyclodextrin (β-CD) and hydroxypropyl-β-cyclodextrin (HP-β-CD) were used to prepare insoluble polymers using epichlorohydrin as a cross-linking agent and the azo dye Direct Red 83:1 was used as target adsorbate. The preliminary study related to adsorbent dosage, pH, agitation or dye concentration allowed us to select the best conditions to carry out the rest of experiments. The kinetics was evaluated by Elovich, pseudo first order, pseudo second order, and intra-particle diffusion models. The results indicated that the pseudo second order model presented the best fit to the experimental data, indicating that chemisorption is controlling the process. The results were also evaluated by Freundlich, Langmuir and Temkin isotherms. According to the determination coefficient (R2), Freunlich gave the best results, which indicates that the adsorption process is happening on heterogeneous surfaces. One interesting parameter obtained from Langmuir isotherm is qmax (maximum adsorption capacity). This value was six times higher when a β-CDs-EPI polymer was employed. The cross-linked polymers were fully characterized by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TGA). Also, morphology and particle size distribution were both assessed. Under optimized conditions, the β-CDs-EPI polymer seems to be a useful device for removing Direct Red 83:1 (close 90%), from aqueous solutions and industrial effluents. Complementarily, non-adsorbed dye was photolyzed by a pulsed light driven advanced oxidation process. The proposed methodology is environmental and economically advantageous, considering the point of view of a sustainable recycling economy in the textile dyeing process.es
dc.language.isoenes
dc.publisherMDPIes
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAdsorptiones
dc.subjectDirect Redes
dc.subject-CDSes
dc.subjectHP--CDses
dc.subjectKineticses
dc.subjectIsothermes
dc.subjectPulsed lightes
dc.titleAdsorption Properties of β- and Hydroxypropyl-β-Cyclodextrins Cross-Linked with Epichlorohydrin in Aqueous Solution. A Sustainable Recycling Strategy in Textile Dyeing Processes
dc.typearticlees
dc.rights.accessRightsopenAccesses
dc.relation.projectIDinfo:eu-repo/grantAgreement/LIFE12/ENV/ES/000309es
dc.journal.titlePolymerses
dc.volume.number11es
dc.description.disciplineCiencias Ambientaleses
dc.identifier.doi10.3390/polym11020252es


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Attribution-NonCommercial-NoDerivatives 4.0 Internacional
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